nach oben

Journal of Sol-Gel Science and Technology

Erschienen in:

23.02.2024 | Original Paper

Selective removal of Cu(II) ions by magnetic mesoporous silica with surface ion-imprinted quaternized Schiff base coating

verfasst von: Qiongxin Gou, Yiying Xiong, Yunqiong Yang, Yuqi Wu, Yuanyuan Zhang

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2024

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The highly selective capture and efficient utilization of recovered Cu(II) ions using a multifunctional material holds substantial practical significance. In this study, a novel type of magnetic adsorbent, MSBA-IIA, was successfully synthesized by grafting a Cu(II) ion-imprinted quaternized salicylaldehyde Schiff base coating onto the surface of magnetic mesoporous silica, aiming to enhance the recognition and separation selectivity for target ions during the adsorption process. Batch Cu(II) ion adsorption experiments demonstrated a dependence of adsorption efficiency on the solution pH level. The Cu(II) adsorption behavior onto MSBA-IIA followed the pseudo-second-order adsorption kinetic model and Langmuir isothermal model. MSBA-IIA exhibited a maximum adsorption capacity of 32.7 mg/g, surpassing that of the non-ion-imprinted counterpart MSBA-NIIA. Thermodynamic study unveiled the spontaneous and exothermic nature of the adsorption process. The relative separation factors α’ of MSBA-IIA for Cu(II) were determined to be much more than 1, suggesting that the imprinted adsorbent exhibited superior selectivity for Cu(II) ions in the presence of other co-existing metal ions when compared to the MSBA-NIIA. Due to its magnetic collection and regenerable nature, the proposed approach holds promise for the selective removal of Cu(II) ions from water.

Graphical Abstract

Vorheriger Artikel Facile synthesis of magnetic-fluorescent iron oxide-geothermal silica core/shell nanocomposites via modified sol–gel method

Nächster Artikel Systematic optimization of sol–gel processed Al-doped ZnO for cost-effective transparent conductive oxide

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Lamichhane JR, Osdaghi E, Behlau F, Köhl J, Jones JB, Aubertot J-N (2018) Thirteen decades of antimicrobial copper compounds applied in agriculture: a review. Agron Sustain Dev 38:28

Wang X, Wang H, Li J, Yang Z, Zhang J, Qin Z, Wang L, Kong X (2014) Evaluation of bioaccumulation and toxic effects of copper on hepatocellular structure in mice. Biol Trace Elem Res 159:312–319PubMed

Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manag 92:407–418

Rajendran S, Priya AK, Senthil Kumar P, Hoang TKA, Sekar K, Chong KY, Khoo KS, Ng HS, Show PL (2022) A critical and recent developments on adsorption technique for removal of heavy metals from wastewater-a review. Chemosphere 303:135146PubMed

Awual MR (2019) Novel ligand functionalized composite material for efficient copper(II) capturing from wastewater sample. Compos B 172:387–396

Salman MS, Hasan MN, Hasan MM, Kubra KT, Sheikh MC, Rehan AI, Waliullah RM, Rasee AI, Awual ME, Hossain MS, Alsukaibi AKD, Alshammari HM, Awual MR (2023) Improving copper(II) ion detection and adsorption from wastewater by the ligand-functionalized composite adsorbent. J Mol Struct 1282:135259

Mihaly-Cozmuta L, Mihaly-Cozmuta A, Peter A, Nicula C, Tutu H, Silipas D, Indrea E (2014) Adsorption of heavy metal cations by Na-clinoptilolite: Equilibrium and selectivity studies. J Environ Manag 137:69–80

El Ouardi Y, Giove A, Laatikainen M, Branger C, Laatikainen K (2021) Benefit of ion imprinting technique in solid-phase extraction of heavy metals, special focus on the last decade. J Environ Chem Eng 9:106548

Fu J, Chen L, Li J, Zhang Z (2015) Current status and challenges of ion imprinting. J Mater Chem A 3:13598–13627

10.

Sharma G, Kandasubramanian B (2020) Molecularly imprinted polymers for selective recognition and extraction of heavy metal ions and toxic dyes. J Chem Eng Data 65:396–418

11.

Wu H, Lin G, Liu C, Chu S, Mo C, Liu X (2022) Progress and challenges in molecularly imprinted polymers for adsorption of heavy metal ions from wastewater. Trends Environ Anal Chem 36:e00178

12.

Fan H-T, Fan X, Li J, Guo M, Zhang D, Yan F, Sun T (2012) Selective removal of Arsenic(V) from aqueous solution using A surface-ion-imprinted amine-functionalized silica gel sorbent. Ind Eng Chem Res 51:5216–5223

13.

Guo B, Deng F, Zhao Y, Luo X, Luo S, Au C (2014) Magnetic ion-imprinted and –SH functionalized polymer for selective removal of Pb(II) from aqueous samples. Appl Surf Sci 292:438–446

14.

Zhang M, Zhang Z, Liu Y, Yang X, Luo L, Chen J, Yao S (2011) Preparation of core–shell magnetic ion-imprinted polymer for selective extraction of Pb(II) from environmental samples. Chem Eng J 178:443–450

15.

Huang R, Shao N, Hou L, Zhu X (2019) Fabrication of an efficient surface ion-imprinted polymer based on sandwich-like graphene oxide composite materials for fast and selective removal of lead ions. Colloids Surf A 566:218–228

16.

He J, Shang H, Zhang X, Sun X (2018) Synthesis and application of ion imprinting polymer coated magnetic multi-walled carbon nanotubes for selective adsorption of nickel ion. Appl Surf Sci 428:110–117

17.

Chen H, Kong J, Yuan D, Fu G (2014) Synthesis of surface molecularly imprinted nanoparticles for recognition of lysozyme using a metal coordination monomer. Biosens Bioelectron 53:5–11PubMed

18.

Ren Z, Zhu X, Du J, Kong D, Wang N, Wang Z, Wang Q, Liu W, Li Q, Zhou Z (2018) Facile and green preparation of novel adsorption materials by combining sol-gel with ion imprinting technology for selective removal of Cu(II) ions from aqueous solution. Appl Surf Sci 435:574–584

19.

Da’na E (2017) Adsorption of heavy metals on functionalized-mesoporous silica: a review. Microporous Mesoporous Mater 247:145–157

20.

Awual MR (2015) A novel facial composite adsorbent for enhanced copper(II) detection and removal from wastewater. Chem Eng J 266:368–375

21.

Kubra KT, Salman MS, Hasan MN, Islam A, Hasan MM, Awual MR (2021) Utilizing an alternative composite material for effective copper(II) ion capturing from wastewater. J Mol Liq 336:116325

22.

Awual MR (2017) New type mesoporous conjugate material for selective optical copper(II) ions monitoring & removal from polluted waters. Chem Eng J 307:85–94

23.

Awual MR, Hasan MM, Khaleque MA, Sheikh MC (2016) Treatment of copper(II) containing wastewater by a newly developed ligand based facial conjugate materials. Chem Eng J 288:368–376

24.

Verma P, Kuwahara Y, Mori K, Raja R, Yamashita H (2020) Functionalized mesoporous SBA-15 silica: recent trends and catalytic applications. Nanoscale 12:11333–11363PubMed

25.

Ghanavati Nasab S, Semnani A, Karimi M, Javaheran Yazd M, Cheshmekhezr S (2019) Synthesis of ion-imprinted polymer-decorated SBA-15 as a selective and efficient system for the removal and extraction of Cu(ii) with focus on optimization by response surface methodology. Analyst 144:4596–4612PubMed

26.

Mao Y, Gou Q, Wu G, Yang Y, Chen M, Zhang Y (2022) Preparation of pyridine Schiff base grafted ion-imprinted mesoporous sorbent for selective separation of Pb(II) from aqueous medium. J Sol Gel Sci Technol 102:454–464

27.

Zhang J, Li X, Rosenholm JM, Gu H-C (2011) Synthesis and characterization of pore size-tunable magnetic mesoporous silica nanoparticles. J Colloid Interface Sci 361:16–24PubMed

28.

Alfonso-Herrera LA, Rosete-Luna S, Hernández-Romero D, Rivera-Villanueva JM, Olivares-Romero JL, Cruz-Navarro JA, Soto-Contreras A, Arenaza-Corona A, Morales-Morales D, Colorado-Peralta R (2022) Transition metal complexes with tridentate schiff bases (O N O and O N N) derived from salicylaldehyde: an analysis of their potential anticancer activity. ChemMedChem 17:e202200367PubMedPubMedCentral

29.

Wang S, Wang K, Dai C, Shi H, Li J (2015) Adsorption of Pb2+ on amino-functionalized core–shell magnetic mesoporous SBA-15 silica composite. Chem Eng J 262:897–903

30.

Liu Y, Fu R, Sun Y, Zhou X, Baig SA, Xu X (2016) Multifunctional nanocomposites Fe3O4@SiO2-EDTA for Pb(II) and Cu(II) removal from aqueous solutions. Appl Surf Sci 369:267–276

31.

Tan L, Xu J, Xue X, Lou Z, Zhu J, Baig SA, Xu X (2014) Multifunctional nanocomposite Fe3O4@SiO2–mPD/SP for selective removal of Pb(ii) and Cr(vi) from aqueous solutions. RSC Adv 4:45920–45929

32.

Zhang Y, Zhu T, Xu Y, Yang Y, Sheng D, Ma Q (2023) Quaternized salicylaldehyde Schiff base side-chain polymer-grafted magnetic Fe3O4 nanoparticles for the removal and detection of Cu2+ ions in water. Appl Surf Sci 611:155632

33.

Hasan MM, Salman MS, Hasan MN, Rehan AI, Awual ME, Rasee AI, Waliullah RM, Hossain MS, Kubra KT, Sheikh MC, Khaleque MA, Marwani HM, Islam A, Awual MR (2023) Facial conjugate adsorbent for sustainable Pb(II) ion monitoring and removal from contaminated water. Colloids Surf, A 673:131794

34.

Awual MR, Hasan MN, Hasan MM, Salman MS, Sheikh MC, Kubra KT, Islam MS, Marwani HM, Islam A, Khaleque MA, Waliullah RM, Hossain MS, Rasee AI, Rehan AI, Awual ME (2023) Green and robust adsorption and recovery of Europium(III) with a mechanism using hybrid donor conjugate materials. Sep Purif Technol 319:124088

35.

Baldovino-Medrano VG, Niño-Celis V, Isaacs Giraldo R (2023) Systematic analysis of the nitrogen adsorption–desorption isotherms recorded for a series of materials based on microporous–mesoporous amorphous aluminosilicates using classical methods. J Chem Eng Data 68:2512–2528

36.

Corma A, García H, Llabrés i Xamena FX (2010) Engineering metal organic frameworks for heterogeneous catalysis. Chem Rev 110:4606–4655PubMed

37.

Al-Bayati HKA, Das PK, Tighe SL, Baaj H (2016) Evaluation of various treatment methods for enhancing the physical and morphological properties of coarse recycled concrete aggregate. Constr Build Mater 112:284–298

38.

Vojoudi H, Badiei A, Bahar S, Mohammadi Ziarani G, Faridbod F, Ganjali MR (2017) A new nano-sorbent for fast and efficient removal of heavy metals from aqueous solutions based on modification of magnetic mesoporous silica nanospheres. J Environ Manag 441:193–203

39.

Almessiere MA, Slimani Y, Ibrahim YO, Gondal MA, Dastageer MA, Auwal IA, Trukhanov AV, Manikandan A, Baykal A (2021) Morphological, structural, and magnetic characterizations of hard-soft ferrite nanocomposites synthesized via pulsed laser ablation in liquid. Mater Sci Eng B 273:115446

40.

Wu H, Xiao Y, Guo Y, Miao S, Chen Q, Chen Z (2020) Functionalization of SBA-15 mesoporous materials with 2-acetylthiophene for adsorption of Cr(III) ions. Microporous Mesoporous Mater 292:109754

41.

Hakiki A, Boukoussa B, Habib Zahmani H, Hamacha R, Hadj Abdelkader NeH, Bekkar F, Bettahar F, Nunes-Beltrao AP, Hacini S, Bengueddach A, Azzouz A (2018) Synthesis and characterization of mesoporous silica SBA-15 functionalized by mono-, di-, and tri-amine and its catalytic behavior towards Michael addition. Mater Chem Phys 212:415–425

42.

Zhang Y, Zhu T, Wang H, Zheng L, Chen M, Wang W (2022) Preparation of a bis-Schiff base immobilized mesoporous SBA-15 nanosensor for the fluorogenic sensing and adsorption of Cu2+. Dalton Trans 51:7210–7222PubMed

43.

Simonin J-P (2016) On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. Chem Eng J 300:254–263

44.

Yuan Q, Li N, Chi Y, Geng W, Yan W, Zhao Y, Li X, Dong B (2013) Effect of large pore size of multifunctional mesoporous microsphere on removal of heavy metal ions. J Hazard Mater 254-255:157–165PubMed

45.

Zhao J, Niu Y, Ren B, Chen H, Zhang S, Jin J, Zhang Y (2018) Synthesis of Schiff base functionalized superparamagnetic Fe3O4 composites for effective removal of Pb(II) and Cd(II) from aqueous solution. Chem Eng J 347:574–584

46.

Lachowicz JI, Delpiano GR, Zanda D, Piludu M, Sanjust E, Monduzzi M, Salis A (2019) Adsorption of Cu2+ and Zn2+ on SBA-15 mesoporous silica functionalized with triethylenetetramine chelating agent. J Environ Chem Eng 7:103205

47.

Araújo CST, Almeida ILS, Rezende HC, Marcionilio SMLO, Léon JJL, de Matos TN (2018) Elucidation of mechanism involved in adsorption of Pb(II) onto lobeira fruit (Solanum lycocarpum) using Langmuir, Freundlich and Temkin isotherms. Microchem J 137:348–354

48.

Verma M, Ahmad W, Park J-H, Kumar V, Vlaskin MS, Vaya D, Kim H (2022) One-step functionalization of chitosan using EDTA: Kinetics and isotherms modeling for multiple heavy metals adsorption and their mechanism. J Water Process Eng 49:102989

49.

Liu Y, Liu Y-J (2008) Biosorption isotherms, kinetics and thermodynamics. Sep Purif Technol 61:229–242

50.

Hao D, Song Y-X, Zhang Y, Fan H-T (2021) Nanocomposites of reduced graphene oxide with pure monoclinic-ZrO2 and pure tetragonal-ZrO2 for selective adsorptive removal of oxytetracycline. Appl Surf Sci 543:148810

51.

Li Y, Wang X, Zou S, Ding Y, You N, Fan H (2022) Nanocomposites of immobilized nano-zirconia on low-cost activated carbon derived from hazelnut shell for enhanced removal of 3-Nitro-4-Hydroxy-Phenylarsonic acid from water. Environ Res 209:112851PubMed

52.

You N, Wang X-F, Li J-Y, Fan H-T, Shen H, Zhang Q (2019) Synergistic removal of arsanilic acid using adsorption and magnetic separation technique based on Fe3O4@ graphene nanocomposite. J Ind Eng Chem 70:346–354

53.

Liu Y (2009) Is the free energy change of adsorption correctly calculated? J Chem Eng Data 54:1981–1985

54.

Ding L, Deng H, Wu C, Han X (2012) Affecting factors, equilibrium, kinetics and thermodynamics of bromide removal from aqueous solutions by MIEX resin. Chem Eng J 181-182:360–370

55.

Raff LM (2014) Spontaneity and equilibrium: why “ΔG < 0 denotes a spontaneous process” and “ΔG = 0 means the system is at equilibrium” are incorrect. J Chem Educ 91:386–395

56.

Rasee AI, Awual E, Rehan AI, Hossain MS, Waliullah RM, Kubra KT, Sheikh MC, Salman MS, Hasan MN, Hasan MM, Marwani HM, Islam A, Khaleque MA, Awual MR (2023) Efficient separation, adsorption, and recovery of Samarium(III) ions using novel ligand-based composite adsorbent. Surf Interfaces 41:103276

57.

Sheikh MC, Hasan MM, Hasan MN, Salman MS, Kubra KT, Awual ME, Waliullah RM, Rasee AI, Rehan AI, Hossain MS, Marwani HM, Islam A, Khaleque MA, Awual MR (2023) Toxic cadmium(II) monitoring and removal from aqueous solution using ligand-based facial composite adsorbent. J Mol Liq 389:122854

58.

Awual MR, Suzuki S, Taguchi T, Shiwaku H, Okamoto Y, Yaita T (2014) Radioactive cesium removal from nuclear wastewater by novel inorganic and conjugate adsorbents. Chem Eng J 242:127–135

59.

Wu F, Li H, Pan Y, Sun Y, Pan J (2023) Bioinspired construction of magnetic nano stirring rods with radially aligned dual mesopores and intrinsic rapid adsorption of palladium. J Hazard Mater 441:129917PubMed

60.

Ndunda EN (2020) Molecularly imprinted polymers—a closer look at the control polymer used in determining the imprinting effect: A mini review. J Mol Recognit 33:e2855PubMed

61.

Chang X, Jiang N, Zheng H, He Q, Hu Z, Zhai Y, Cui Y (2007) Solid-phase extraction of iron(III) with an ion-imprinted functionalized silica gel sorbent prepared by a surface imprinting technique. Talanta 71:38–43PubMed

62.

Daughney CJ, Fein JB (1998) The effect of ionic strength on the adsorption of H+, Cd2+, Pb2+, and Cu2+byBacillus subtilis and bacillus licheniformis:a surface complexation model. J Colloid Interface Sci 198:53–77

63.

Wondracek MHP, Jorgetto AO, Silva ACP, Ivassechen JDR, Schneider JF, Saeki MJ, Pedrosa VA, Yoshito WK, Colauto F, Ortiz WA, Castro GR (2016) Synthesis of mesoporous silica-coated magnetic nanoparticles modified with 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole and its application as Cu(II) adsorbent from aqueous samples. Appl Surf Sci 367:533–541

64.

Wang F, Guo C, Yang L-R, Liu C-Z (2010) Magnetic mesoporous silica nanoparticles: fabrication and their laccase immobilization performance. Bioresour Technol 101:8931–8935PubMed

65.

Anbia M, Kargosha K, Khoshbooei S (2015) Heavy metal ions removal from aqueous media by modified magnetic mesoporous silica MCM-48. Chem Eng Res Des 93:779–788

66.

Zhang M, Wang W, Zhu Z, Qu C, Zhou Q, Wang S, Ding L (2018) One-step synthesis of amino-functionalised magnetic mesoporous silica and synergistic adsorption kinetics of tetracycline and copper. in: Micro Nano Lett., Institution of Engineering and Technology, pp. 1219–1223.

67.

Hassan M, Naidu R, Du J, Qi F, Ahsan MA, Liu Y (2022) Magnetic responsive mesoporous alginate/β-cyclodextrin polymer beads enhance selectivity and adsorption of heavy metal ions. Int J Biol Macromol 207:826–840PubMed

Titel: Selective removal of Cu(II) ions by magnetic mesoporous silica with surface ion-imprinted quaternized Schiff base coating
verfasst von: Qiongxin Gou
Yiying Xiong
Yunqiong Yang
Yuqi Wu
Yuanyuan Zhang
Publikationsdatum: 23.02.2024
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 1/2024
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-024-06309-9

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Graphical Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 1/2024

Investigation of the effect of graphene oxide nanoparticles on the structural and dielectric parameters in zinc oxide semiconductors

Perovskite-type catalyst for tetracycline abatement under dark ambient over a wide pH range

A facile synthesis and characterization of spinel Zinc-Chromite (ZnCr2O4) nanoparticles: their photocatalytic, antibacterial, and anticancer activities

Low-temperature microwave hydrothermally synthesized Mn-doped NiCo2O4 nanoparticles: enhanced structural and electrochemical properties

Template free aqueous solution synthesized microporous In2S3 for water purification

Effectiveness of photocatalysis of Fe78Si9B13/TiO2 composites for acid orange 7 degradation

Premium Partner

Marktübersichten