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Physics of Metals and Metallography

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01.12.2023 | STRENGTH AND PLASTICITY

Structure, Phase Composition, and Mechanical Properties of a High Strength Steel with Transition Carbide η-Fe₂C

verfasst von: Yu. I. Borisova, R. V. Mishnev, E. S. Tkachev, T. V. Kniaziuk, S. M. Gaidar, R. O. Kaibyshev

Erschienen in: Physics of Metals and Metallography | Ausgabe 12/2023

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Abstract—

The effects of quenching and tempering on the structure, phase composition, and mechanical properties of the Fe–0.34C high strength steel with 1.77 wt % Si are studied. The tempering at temperatures up to 500°C barely has an effect on the structural characteristics of packet martensite formed during quenching. The precipitation of intermediate (transition) η-carbide particles at tempering temperatures in the range of 200–400°C leads to increases in the yield strength to 1490 MPa and in the impact toughness to 35 J/cm². The determined temperature of the ductile–brittle transition of the steel tempered at 200°C is about –50°C. A decrease in the impact toughness and a decrease in the proportion of ductile fracture with a decrease in the test temperature are accompanied by a transition from transgranular to intergranular fracture. The precipitation of cementite particles along the boundaries of the laths and blocks is observed after tempering at 500°C. This leads to a decrease in the yield strength, while the impact toughness of the steel remains unchanged.

Vorheriger Artikel Dynamic Properties of Low-Alloyed Copper Alloys with Submicrocrystalline Structure Obtained by High Strain Rate Deformation

Nächster Artikel Mechanical Properties of High Entropy Alloys Based on Rare Earth Elements with Yttrium and Scandium

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V. V. Ryabov, E. I. Khlusova, S. A. Golosienko, and G. D. Motovilina, “New steels for agricultural machine building,” Metallurgist 59, 505–513 (2015). https://doi.org/10.1007/s11015-015-0132-3CrossRef

N. Fonstein, Advanced High Strength Sheet Steels: Physical Metallurgy, Design, Processing, and Properties (Springer, Cham, 2015). https://doi.org/10.1007/978-3-319-19165-2CrossRef

J. Zhao and Z. Jiang, “Thermomechanical processing of advanced high strength steels,” Prog. Mater. Sci. 94, 174–242 (2018). https://doi.org/10.1016/j.pmatsci.2018.01.006CrossRef

G. Malakondaiah, M. Srinivas, and P. R. Rao, “Ultrahigh-strength low-alloy steels with enhanced fracture toughness,” Prog. Mater. Sci. 42, 209–242 (1997). https://doi.org/10.1016/s0079-6425(97)00016-9CrossRef

J. Li, D. Zhan, Z. Jiang, H. Zhang, Yo. Yang, and Ya. Zhang, “Progress on improving strength-toughness of ultra-high strength martensitic steels for aerospace applications: A review,” J. Mater. Res. Technol. 23, 172–190 (2023). https://doi.org/10.1016/j.jmrt.2022.12.177CrossRef

G. Krauss, “Steels,” in Processing Structure, and Performance (ASM Int., Metals Park, Ohio, 2005), pp. 230–232. https://doi.org/10.31399/asm.tb.spsp2.9781627082655

Y. Tomita, “Development of fracture toughness of ultrahigh strength, medium carbon, low alloy steels for aerospace applications,” Int. Mater. Rev. 45, 27–37 (2000). https://doi.org/10.1179/095066000771048791CrossRef

R. Mishnev, Yu. Borisova, T. Kniaziuk, S. Gaidar, and R. Kaibyshev, “Quench and tempered embrittlement of ultra-high-strength steels with transition carbides,” Metals 13, 1399 (2023). https://doi.org/10.3390/met13081399CrossRef

S. Borisov, Yu. Borisova, E. Tkachev, T. Kniaziuk, and R. Kaibyshev, “Tempering behavior of a Si-rich low-alloy medium-carbon steel,” Metals 13, 1403 (2023). https://doi.org/10.3390/met13081403CrossRef

10.

E. Tkachev, S. Borisov, A. Belyakov, T. Kniaziuk, O. Vagina, S. Gaidar, and R. Kaibyshev, “Effect of quenching and tempering on structure and mechanical properties of a low-alloy 0.25C steel,” Mater. Sci. Eng., A 868, 144757 (2023). https://doi.org/10.1016/j.msea.2023.144757CrossRef

11.

V. Dudko, D. Yuzbekova, S. Gaidar, S. Vetrova, and R. Kaibyshev, “Tempering behavior of novel low-alloy high-strength steel,” Metals 12, 2177 (2022). https://doi.org/10.3390/met12122177CrossRef

12.

V. K. Euser, D. L. Williamson, K. O. Findley, A. J. Clarke, and J. G. Speer, “The role of retained austenite in tempered martensite embrittlement of 4340 and 300-M steels investigated through rapid tempering,” Metals 11, 1349 (2021). https://doi.org/10.3390/met11091349CrossRef

13.

V. M. Schastlivtsev, Yu. V. Kaletina, E. A. Fokina, and A. Yu. Kaletin, “On the role of retained austenite in the structure of alloyed steels and the effect of external factors,” Phys. Met. Metallogr. 115, 904–917 (2014). https://doi.org/10.1134/s0031918x14090105ADSCrossRef

14.

L. Liu, B. R. Shan, Z. H. Zhang, T. T. Li, S. Z. Zhao, C. N. Jing, T. Lin, and J. R. Zhao, “Effect of cyclic quenching on the austenite stability and work hardening behavior of medium-Mn quenching and partitioning steel enabled by intercritical annealing,” Phys. Met. Metallogr. 123, 1451–1460 (2022). https://doi.org/10.1134/s0031918x2110104xADSCrossRef

15.

J. G. Speer, “Phase transformations in quenched and partitioned steels,” in Phase Transformations in Steels: Diffusionless Transformations, High Strength Steels, Modelling and Advanced Analytical Techniques, Ed. by E. Pereloma and D. V. Edmonds, Woodhead Publishing Series in Metals and Surface Engineering, Vol. 2 (Elsevier, Cambridge, 2012), pp. 247–270. https://doi.org/10.1533/9780857096111.2.247

16.

E. Kozeschnik and H. K. D. H. Bhadeshia, “Influence of silicon on cementite precipitation in steels,” Mater. Sci. Technol. 24, 343–347 (2008). https://doi.org/10.1179/174328408x275973ADSCrossRef

17.

H. K. D. H. Bhadeshia, D. E. Laughlin, and K. Hono, “Physical metallurgy of steels,” in Physical Metallurgy, Ed. by D. E. Laughlin and K. Hono (Elsevier, Amsterdam, 2014), pp. 2157–2214. https://doi.org/10.1016/b978-0-444-53770-6.00021-6CrossRef

18.

D. A. Porter, K. E. Easterling, and M. Y. Sherif, Phase Transformations in Metals and Alloys (CRC Press, Boca Raton, Fla., 2009). https://doi.org/10.1201/9781003011804CrossRef

19.

M. V. Maisuradze, Yu. V. Yudin, A. A. Kuklina, and D. I. Lebedev, “Formation of microstructure and properties during isothermal treatment of aircraft building steel,” Metallurgist 65, 1008–1019 (2022). https://doi.org/10.1007/s11015-022-01241-1CrossRef

20.

S. Vervynckt, K. Verbeken, B. Lopez, and J. J. Jonas, “Modern HSLA steels and role of non-recrystallisation temperature,” Int. Mater. Rev. 57, 187–207 (2012). https://doi.org/10.1179/1743280411y.0000000013CrossRef

21.

D. P. Field, “Recent advances in the application of orientation imaging,” Ultramicroscopy 67, 1–9 (1997). https://doi.org/10.1016/s0304-3991(96)00104-0CrossRef

22.

F. Niessen, T. Nyyssönen, A. A. Gazder, and R. Hielscher, “Parent grain reconstruction from partially or fully transformed microstructures in MTEX,” J. Appl. Crystallogr. 55, 180–194 (2022). https://doi.org/10.1107/s1600576721011560ADSCrossRefPubMedPubMedCentral

23.

M. Calcagnotto, D. Ponge, E. Demir, and D. Raabe, “Orientation gradients and geometrically necessary dislocations in ultrafine grained dual-phase steels studied by 2D and 3D EBSD,” Mater. Sci. Eng., A 527, 2738–2746 (2010). https://doi.org/10.1016/j.msea.2010.01.004CrossRef

24.

R. Mishnev, Yu. Borisova, S. Gaidar, T. Kniaziuk, O. Vagina, and R. Kaibyshev, “Q&P response of a medium carbon low alloy steel,” Metals 13, 689 (2023). https://doi.org/10.3390/met13040689CrossRef

25.

T. Wang, J. Du, and F. Liu, “Modeling competitive precipitations among iron carbides during low-temperature tempering of martensitic carbon steel,” Materialia 12, 100800 (2020). https://doi.org/10.1016/j.mtla.2020.100800CrossRef

26.

D. T. Pierce, D. R. Coughlin, D. L. Williamson, K. D. Clarke, A. J. Clarke, J. G. Speer, and E. De Moor, “Characterization of transition carbides in quench and partitioned steel microstructures by Mössbauer spectroscopy and complementary techniques,” Acta Mater. 90, 417–430 (2015). https://doi.org/10.1016/j.actamat.2015.01.024ADSCrossRef

27.

W. Lu, M. Herbig, C. H. Liebscher, L. Morsdorf, R. K. W. Marceau, G. Dehm, and D. Raabe, “Formation of eta carbide in ferrous martensite by room temperature aging,” Acta Mater. 158, 297–312 (2018). https://doi.org/10.1016/j.actamat.2018.07.071ADSCrossRef

28.

Z. Xiong, I. Timokhina, and E. Pereloma, “Clustering, nano-scale precipitation and strengthening of steels,” Prog. Mater. Sci. 118, 100764 (2021). https://doi.org/10.1016/j.pmatsci.2020.100764CrossRef

29.

R. M. Horn and R. O. Ritchie, “Mechanisms of tempered martensite embrittlement in low alloy steels,” Metall. Trans. A 9, 1039–1053 (1978). https://doi.org/10.1007/bf02652208CrossRef

30.

H. Kitahara, R. Ueji, N. Tsuji, and Yo. Minamino, “Crystallographic features of lath martensite in low-carbon steel,” Acta Mater. 54, 1279–1288 (2006). https://doi.org/10.1016/j.actamat.2005.11.001ADSCrossRef

31.

G. Miyamoto, N. Iwata, N. Takayama, and T. Furuhara, “Mapping the parent austenite orientation reconstructed from the orientation of martensite by EBSD and its application to ausformed martensite,” Acta Mater. 58, 6393–6403 (2010). https://doi.org/10.1016/j.actamat.2010.08.001ADSCrossRef

32.

V. M. Gundyrev, V. I. Zeldovich, and V. M. Schastlivtsev, “Crystallographic analysis and mechanism of martensitic transformation in Fe alloys,” Phys. Met. Metallogr. 121, 1045–1063 (2020). https://doi.org/10.1134/s0031918x20110046ADSCrossRef

33.

E. I. Galindo-Nava and P. E. J. Rivera-Díaz-Del-Castillo, “A model for the microstructure behaviour and strength evolution in lath martensite,” Acta Mater. 98, 81–93 (2015). https://doi.org/10.1016/j.actamat.2015.07.018ADSCrossRef

34.

N. Nakada, Yu. Ishibashi, T. Tsuchiyama, and S. Takaki, “Self-stabilization of untransformed austenite by hydrostatic pressure via martensitic transformation,” Acta Mater. 110, 95–102 (2016). https://doi.org/10.1016/j.actamat.2016.03.048ADSCrossRef

35.

R. A. Vorobev, V. N. Dubinskii, and V. V. Evstifeeva, “Effect of the processes of self-tempering and tempering on the mechanical characteristics and the character of fracture of low-carbon martenstic steel quenched in air,” Phys. Met. Metallogr. 120, 989–994 (2019). https://doi.org/10.1134/S0031918X19100132ADSCrossRef

36.

V. Dudko, A. Belyakov, and R. Kaibyshev, “Evolution of lath substructure and internal stresses in a 9% Cr steel during creep,” ISIJ Int. 57, 540–549 (2017). https://doi.org/10.2355/isijinternational.isijint-2016-334CrossRef

37.

M. V. Odnobokova, A. Yu. Kipelova, A. N. Belyakov, and R. O. Kaibyshev, “Mechanical behavior and brittle–ductile transition of high-chromium martensitic steel,” Phys. Met. Metallogr. 117, 390–398 (2016). https://doi.org/10.1134/s0031918x16040098ADSCrossRef

38.

J. Inoue, A. Sadeghi, and T. Koseki, “Slip band formation at free surface of lath martensite in low carbon steel,” Acta Mater. 165, 129–141 (2019). https://doi.org/10.1016/j.actamat.2018.11.026ADSCrossRef

39.

C. L. Briant, “Role of carbides in tempered martensite embrittlement,” Mater. Sci. Technol. 5, 138–147 (1989). https://doi.org/10.1179/mst.1989.5.2.138ADSCrossRef

40.

A. Chatterjee, A. Moitra, A. K. Bhaduri, D. Chakrabarti, and R. Mitra, “Effect of heat treatment on ductile-brittle transition behaviour of 9Cr–1Mo steel,” Procedia Eng. 86, 287–294 (2014). https://doi.org/10.1016/j.proeng.2014.11.040CrossRef

41.

Mechanical Testing and Evaluation, Ed. by H. Kuhn and D. Medlin, ASM Handbook, Vol. 8 (ASM International, 2000). https://doi.org/10.31399/asm.hb.v08.9781627081764CrossRef

42.

G. Krauss and D. K. Matlock, “Effects of strain hardening and fine structure on strength and toughness of tempered martensite in carbon steels,” J. Physique IV 05, C8–51 (1995). https://doi.org/10.1051/jp4:1995806CrossRef

43.

T. Hanamura, F. Yin, and K. Nagai, “Ductile–brittle transition temperature of ultrafine ferrite/cementite microstructure in a low carbon steel controlled by effective grain size,” ISIJ Int. 44, 610–617 (2004). https://doi.org/10.2355/isijinternational.44.610CrossRef

44.

J. W. Morris Jr., “On the ductile–brittle transition in lath martensitic steel,” ISIJ Int. 51, 1569–1575 (2011). https://doi.org/10.2355/isijinternational.51.1569CrossRef

Titel: Structure, Phase Composition, and Mechanical Properties of a High Strength Steel with Transition Carbide η-Fe2C
verfasst von: Yu. I. Borisova
R. V. Mishnev
E. S. Tkachev
T. V. Kniaziuk
S. M. Gaidar
R. O. Kaibyshev
Publikationsdatum: 01.12.2023
Verlag: Pleiades Publishing
Erschienen in: Physics of Metals and Metallography / Ausgabe 12/2023
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI: https://doi.org/10.1134/S0031918X23602445

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