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18.05.2024 | Metals & corrosion

Substrate-dependent structural evolution during the oxidation of SiNx thin films

verfasst von: Gowun Jung, Sehun Kim, Jiho Eom, In Young Song, Jinhee Lee, Seong-Keun Cho, Wang-Eun Lee, Kyuyoung Heo, Tae-Yeon Cho, Hwanhui Yun

Erschienen in: Journal of Materials Science

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Abstract

SiNx thin films have garnered attention as promising barrier films, primarily due to their low impurity diffusion rates, making them suitable for various technological applications. Despite their potential, these films face challenges because they are prone to degradation in hostile environments. This study investigated the oxidation behavior of SiNx thin films, particularly when deposited on two different types of substrates: rigid silicon (Si) and flexible polyethylene terephthalate (PET) films. A thorough microstructural analysis of the SiNx films reveals their detailed morphological and compositional characteristics, enabling a comparison between the SiNx/Si and SiNx/PET films. This study further investigates the impacts of high-temperature and humidity exposure on SiNx thin films, systematically elucidating the degradation behaviors and underlying mechanisms. The structural evolution during SiNx film oxidation is illustrated at the nanoscale, and the factors contributing to the oxidation were analyzed. This study deepens our understanding of the interplay between oxidation processes and the unique environmental conditions of substrates, offering insights into enhancing the stability and reliability of these materials.

Graphical abstract

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Metadaten
Titel
Substrate-dependent structural evolution during the oxidation of SiNx thin films
verfasst von
Gowun Jung
Sehun Kim
Jiho Eom
In Young Song
Jinhee Lee
Seong-Keun Cho
Wang-Eun Lee
Kyuyoung Heo
Tae-Yeon Cho
Hwanhui Yun
Publikationsdatum
18.05.2024
Verlag
Springer US
Erschienen in
Journal of Materials Science
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-024-09751-w

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