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Journal of Materials Science: Materials in Electronics

20.01.2020

Synthesis and dielectric spectroscopic study of lead-free ferroelectric ceramic K0.5Bi0.5TiO3-NaNbO3

verfasst von: S. K. Mohanty, Debi Prasad Datta, B. Behera, Hari Sankar Mohanty, Biswajit Pati, Piyush R. Das

Erschienen in: Journal of Materials Science: Materials in Electronics

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Abstract

We report the synthesis and promising electrical properties of a new lead-free ferroelectric ceramic K0.5Bi0.5TiO3-NaNbO3 (KBT-NN), which can be a candidate of choice for future sensors, FeRAM etc. Mixed-oxide method has been employed to prepare the compound comprising of uniformly distributed grains. Detailed structural analysis revealed its orthorhombic structure with space group Pmc21. In-depth analysis of the electrical characterization data revealed a band-gap of 3.11 eV and presence of defects in the bands. Further, ferroelectric phase transition is observed to occur at 395 °C. The dielectric properties of the material, investigated over a wide range of frequencies and temperatures, indicate that its ac conductivity depends upon frequency according to Jonscher’s power law.

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Literatur
1.
G.H. Haertling, Ferroelectric ceramics: history and technology. J. Am. Ceram. Soc. 82, 797–818 (1999)
2.
M.E. Lines, A.M. Glass, Principle and Application of Ferroelectrics and Related Materials (Clarndon Press, Oxford, 1977)
3.
R. Selvamani, G. Singh, V. Sathe, V.S. Tiwari, P.K. Gupta, Dielectric, structural and Raman studies on (Na0.5Bi0.5TiO3)(1−x)(BiCrO3)x ceramic. J. Phys. 23, 8 (2011)
4.
A.I. Kingon, P.J. Terblanché, J.B. Clark, The control of composition, microstructure and properties of Pb(Zr, Ti)O3 ceramics. Mater. Sci. Eng. B 71, 391–397 (1985)
5.
V.V. Shvartsman, J. Dec, T. Lukasiewicz, A.L. Khalkin, W.K. Leemann, Evolution of the polar structure in relaxor ferroelectrics close to the curie temperature studied by piezoresponse force microscopy. Ferroelectrics 373, 77–85 (2008)
6.
S. Zhao, Q. Li, Y. Feng, C. Nan, Microstructure and dielectric properties of PMN–PT ceramics prepared by the molten salts method. J. Phys. Chem. Solids 70, 639–644 (2009)
7.
Z. Yu, C. Ang, R. Guo, A.S. Bhalla, Piezoelectric and strain properties of Ba(Ti1−xZrx)O3 ceramics. J. Appl. Phys. 92, 1489–1493 (2002)
8.
C. Karthik, N. Ravishankar, K.B.R. Varma, M. Maglione, R. Vondermuhll, J. Etourneau, Relaxor behaviour of K0.5La0.5Bi2Nb2O9 ceramic. Appl. Phys. Lett. 89, 042905–042913 (2006)
9.
R. Zuo, D. Lv, J. Fu, Y. Liu, L. Li, Phase transition and electrical properties of lead free (Na0.5K0.5)NbO3–BiAlO3 ceramics. J. Alloys Compd. 476, 836–839 (2009)
10.
Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamur, Lead-free piezoceramics. Nature 432, 84–87 (2004)
11.
B. Jaffe, W.R. Cook, H. Jaffe, Piezoelectric ceramics (Academic Press, London, 1971)
12.
S. Lanfredi, M.H. Lente, J.A. Eiras, Phase transition at low temperature in NaNbO3 ceramic. Appl. Phys. Lett. 80, 2731–2733 (2002)
13.
S. Tripathi, D. Pandey, S.K. Mishra, P.S.R. Krishna, Morphotropic phase-boundary-like characteristic in a lead-free and non-ferroelectric (1–x)NaNbO3−xCaTiO3 system. Phys. Rev. B 77, 052104–52114 (2008)
14.
J.T. Zeng, K.W. Kwok, H.L.W. Chan, Ferroelectric and Piezoelectric Properties of Na1−xBaxNb1−xTixO3 Ceramics. J. Am. Ceram. Soc. 89, 2828–2832 (2006)
15.
M.T. Benlahrache, N. Benhamla, S. Achour, Dielectric properties of BaTiO3–NaNbO3 composites. J. Euro. Ceram. Soc. 24, 1493–1496 (2004)
16.
H. Wu, A. Navrotsky, Y. Su, M.L. Balmer, Perovskite solid solutions along the NaNbO3−SrTiO3 join: phase transitions, formation enthalpies, and implications for general perovskite energetics. Chem. Mater. 17, 1880–1886 (2005)
17.
A. Aydi, H. Khemakhem, C. Boudaya, R.V. Mühll, New ferroelectric and relaxor ceramics in the mixed oxide system NaNbO3–BaSnO3. Solid State Sci. 6, 333–337 (2004)
18.
C. Chaker, W.E. Gharbi, N. Abdelmoula, H. Khemakhem, A. Simon, M. Maglione, Physical properties of the new ceramics in the mixed oxide system Na1−xLixNb1−xSbxO3. J. Alloys Compd. 481, 305–309 (2009)
19.
G. Wang, Z. Lu, Z. Zhang, A. Feteira, C.C. Tang, D.A. Hall, Electric field‐induced irreversible relaxor to ferroelectric phase transformations in Na0.5Bi0.5TiO3‐NaNbO3 ceramics. J. Am. Ceram. Soc. 102, 7746–7754 (2019)
20.
G. Wang, D.A. Hall, T.P. Comyn, L. Daniel, A.K. Kleppe, Structure and ferroelectric behaviour of Na0.5Bi0.5TiO3-KNbO3 ceramics. Adv. Appl. Ceram. Struct. Funct. Bioceram. 115, 89–95 (2016)
21.
J. Ye, G. Wang, M. Zhou, N. Liu, X. Chen, S. Li, F. Cao, X. Dong, Excellent comprehensive energy storage properties of novel lead-free NaNbO3-based ceramics for dielectric capacitor applications. J. Mater. Chem. C 7, 5639–5645 (2019)
22.
Q. Xu, T. Li, H. Hao, S. Zhang, Z. Wang, M. Cao, Z. Yao, H. Liu, Enhanced energy storage properties of NaNbO3 modified Bi0.5Na0.5TiO3 based ceramics. J. Eur. Ceram. Soc. 35, 545–553 (2015)
23.
D. Lin, K.W. Kwok, J. Mater. Sci. 21, 1060 (2010)
24.
J.R. Macdonald, Impedance Spectroscopy Emphasizing Solid Materials and Systems (Chapter-4) (Wiley, New York, 1987)
25.
A.P. Barranco, M.P.G. Amador, A. Huanosta, R. Valenzuela, Appl. Phys. Lett. 73, 20 (1998)
26.
J.R. Carvajal, Recent advances in magnetic structure determination by neutron powder diffraction. Phys B 192, 55–69 (1993)
27.
H.P. Klug, L.B. Alexander, X-ray Diffraction Procedures (Wiley, New York, 1974)
28.
M.F. Mostafa, S.S. Ata-Allah, A.A.A. Youssef, H.S. Refai, Electric and AC magnetic investigation of the manganites La0.7Ca0.3Mn0.96In0.04xAl(1−x)0.04O3; (0.0 ≤ x ≤ 1.0). J. Magn. Magn. Mater. 320, 344–353 (2008)
29.
S. Coste, A. Lecomte, P. Thomas, T. Merle-Mejean, J.C. Champarnaud-Mesjard, Sol-gel synthesis of TeO2-based materials using citric acid as hydrolysis modifier. J. Sol-Gel Sci. Technol. 41, 79–86 (2007)
30.
E.A. Perianu, I.A. Gorodea, F. Gheorghiu, A.V. Sandu, A.C. Ianculescu, I. Sandu, A.R. Iordan, M.N. Palamaru, Rev Chim (Bucharest) 62, 17–20 (2011)
31.
R.L. Frost, J. Yang, Z. Ding, Raman and FTIR spectroscopy of natural oxalates: Implications for the evidence of life on Mars. Chin. Sci. Bull. 48, 1844–1852 (2003)
32.
M. Zheng-Zheng, L. Jian-Qing, T.Z. Ming, Q. Yang, Y. Song-Liu, Improved multiferroic properties of La-doped 0.6BiFeO3–0.4SrTiO3 solid solution ceramic. Chin. Phys. B 21, 107503–107506 (2012)
33.
34.
L. Chen, K.J. Chen, S. Hu, R.S. Liu, Combinatorial chemistry approach to searching phosphors for white light-emitting diodes in (Gd-Y-Bi-Eu)VO4 quaternary system. J. Mater. Chem. 21, 3677–3685 (2011)
35.
B. Liu, X. Wang, G. Cai, L. Wen, Y. Song, X. Zhao, Low temperature fabrication of V-doped TiO2 nanoparticles, structure and photocatalytic studies. J. Hazard. Mater. 169, 1112–1118 (2009)
36.
Y. Hou, M. Zhu, L. Hou, J. Liu, J. Tang, H. Wang, H. Yan, Synthesis and characterization of lead-free K0.5Bi0.5TiO3 ferroelectrics by sol–gel technique. J. Cryst. Growth 273, 500–503 (2005)
37.
H. Idink, V. Srikanth, W.B. White, E.C. Subbarao, Raman study of low temperature phase transitions in bismuth titanate, Bi4Ti3O12. J. Appl. Phys. 76, 1819–1823 (1994)
38.
J.C. Anderson, Dielectrics (Chapman & Hall, London, 1964)
39.
S.M. Pilgrim, A.E. Sutherland, S.R. Winzer, Diffuseness as a useful parameter for relaxor ceramics. J. Am. Ceram. Soc. 73, 3122–3125 (1990)
40.
L.E. Cross, Relaxor ferroelectrics. Ferroelectrics 76, 241–267 (1987)
41.
J.R. Macdonald, Impedance Spectroscopy Emphasizing Solid Materials and Systems, Chapter-4 (Wiley, New York, 1987)
42.
V. Provenzano, L.P. Boesch, V. Volterra, C.T. Moynihan, P.B. Macedo, Electrical relaxation in Na2O.3SiO2 glass. J. Am. Ceram. Soc. 55, 492–496 (1972)
43.
T. Sahu, A.K. Patra, B. Behera, Effect of Gadolinium doping on structural, ferroic and electrical properties of 0.8BiGdxFe1-xO3–0.2PbTiO3 (x = 0.00, 0.05, 0.10, 0.15 and 0.20) composites. J. Alloys Compd. 695, 2273–2284 (2017)
44.
A.K. Jonscher, The universal dielectric response. Nature 267, 673–679 (1977)
45.
I.M. Hodge, M.D. Ingram, A.R. West, A new method for analyzing the a.c. behaviour of polycrystalline solid electrolytes. J. Electroanal. Chem. 58, 429–432 (1975)
46.
J.R. Macdonald, Note on parameterization of the constant-phase admittance element. Solid State Ionics 13, 147–149 (1984)
47.
D.K. Pradhan, R.N.P. Choudhary, C. Rinaldi, R.S. Katiyar, Effect of Mn substitution on electrical and magnetic properties of Bi0.9La0.1FeO3. J. Appl. Phys. 106, 024102–024110 (2009)
48.
H. Jain, C.H. Hsieh, ‘Window’ effect in the analysis of frequency dependence of ionic conductivity. J. Non-Cryst. Solids 172, 1408–1412 (1994)
49.
D.K. Pradhan, B. Behera, P.R. Das, Studies of dielectric and electrical properties of a new type of complex tungsten bronze electro ceramics. J. Mater. Sci. 23, 779–785 (2012)
50.
Z. Lu, J.P. Bonnet, J. Ravez, J.P. Hagenmuller, Correlation between low frequency dielectric dispersion (LFDD) and impedance relaxation in ferroelectric ceramic Pb2KNb4TaO15. Solid State Ionics 57, 235–244 (1992)
Metadaten
Titel
Synthesis and dielectric spectroscopic study of lead-free ferroelectric ceramic K0.5Bi0.5TiO3-NaNbO3
verfasst von
S. K. Mohanty
Debi Prasad Datta
B. Behera
Hari Sankar Mohanty
Biswajit Pati
Piyush R. Das
Publikationsdatum
20.01.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-02873-2